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Metallic hydrogen, once theory, becomes reality

Metallic hydrogen, once theory, becomes reality

Image of diamond anvils compressing molecular hydrogen. At higher pressure the sample converts to atomic hydrogen, as shown on the right. Credit: R. Dias and I.F. Silvera

Nearly a century after it was theorized, Harvard scientists have succeeded in creating the rarest – and potentially one of the most valuable – materials on the planet.

The material – atomic  – was created by Thomas D. Cabot Professor of the Natural Sciences Isaac Silvera and post-doctoral fellow Ranga Dias. In addition to helping scientists answer fundamental questions about the nature of matter, the material is theorized to have a wide range of applications, including as a . The creation of the rare material is described in a January 26 paper published in Science.

“This is the holy grail of high-pressure physics,” Silvera said. “It’s the first-ever sample of metallic hydrogen on Earth, so when you’re looking at it, you’re looking at something that’s never existed before.”

To create it, Silvera and Dias squeezed a tiny hydrogen sample at 495 gigapascal, or more than 71.7 million pounds-per-square inch – greater than the pressure at the center of the Earth. At those extreme pressures, Silvera explained, solid molecular hydrogen -which consists of molecules on the lattice sites of the solid – breaks down, and the tightly bound molecules dissociate to transforms into , which is a metal.

While the work offers an important new window into understanding the general properties of hydrogen, it also offers tantalizing hints at potentially revolutionary new .

“One prediction that’s very important is metallic hydrogen is predicted to be meta-stable,” Silvera said. “That means if you take the pressure off, it will stay metallic, similar to the way diamonds form from graphite under intense heat and pressure, but remains a diamond when that pressure and heat is removed.”

Understanding whether the material is stable is important, Silvera said, because predictions suggest metallic hydrogen could act as a superconductor at room temperatures.

“That would be revolutionary,” he said. “As much as 15 percent of energy is lost to dissipation during transmission, so if you could make wires from this material and use them in the electrical grid, it could change that story.”

Among the holy grails of physics, a room temperature superconductor, Dias said, could radically change our transportation system, making magnetic levitation of high-speed trains possible, as well as making electric cars more efficient and improving the performance of many electronic devices.

The material could also provide major improvements in energy production and storage – because superconductors have zero resistance energy could be stored by maintaining currents in superconducting coils, and then be used when needed.

Metallic hydrogen, once theory, becomes reality
Photos of compressed hydrogen transitioning with increasing pressure from transparent molecular to black molecular to atomic metallic hydrogen. The sketches below show a molecular solid being compressed and then dissociated to atomic hydrogen. Credit: R. Dias and I.F. Silvera

Though it has the potential to transform life on Earth, metallic hydrogen could also play a key role in helping humans explore the far reaches of space, as the most powerful rocket propellant yet discovered.

“It takes a tremendous amount of energy to make metallic hydrogen,” Silvera explained. “And if you convert it back to molecular hydrogen, all that energy is released, so it would make it the most powerful rocket propellant known to man, and could revolutionize rocketry.”

The most powerful fuels in use today are characterized by a “specific impulse” – a measure, in seconds, of how fast a propellant is fired from the back of a rocket – of 450 seconds. The specific impulse for metallic hydrogen, by comparison, is theorized to be 1,700 seconds.

“That would easily allow you to explore the outer planets,” Silvera said. “We would be able to put rockets into orbit with only one stage, versus two, and could send up larger payloads, so it could be very important.”

To create the new material, Silvera and Dias turned to one of the hardest materials on Earth – diamond.

But rather than natural diamond, Silvera and Dias used two small pieces of carefully polished synthetic diamond which were then treated to make them even tougher and then mounted opposite each other in a device known as a .

“Diamonds are polished with diamond powder, and that can gouge out carbon from the surface,” Silvera said. “When we looked at the diamond using atomic force microscopy, we found defects, which could cause it to weaken and break.”

The solution, he said, was to use a reactive ion etching process to shave a tiny layer – just five microns thick, or about one-tenth of a human hair – from the diamond’s surface. The diamonds were then coated with a thin layer of alumina to prevent the hydrogen from diffusing into their crystal structure and embrittling them.

After more than four decades of work on metallic hydrogen, and nearly a century after it was first theorized, seeing the material for the first time, Silvera said, was thrilling.

“It was really exciting,” he said. “Ranga was running the experiment, and we thought we might get there, but when he called me and said, ‘The sample is shining,’ I went running down there, and it was metallic hydrogen.

“I immediately said we have to make the measurements to confirm it, so we rearranged the lab…and that’s what we did,” he said. “It’s a tremendous achievement, and even if it only exists in this diamond anvil cell at high pressure, it’s a very fundamental and transformative discovery.”

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Verlinde’s new theory of gravity passes first test

Verlindes new theory of gravity passes first test

The gravity of galaxies bends space, such that the light traveling through this space is bent. This bending of light allows astronomers to measure the distribution of gravity around galaxies, even up to distances a hundred times larger than the galaxy itself. Credit: APS/Alan Stonebraker; galaxy images from STScI/AURA, NASA, ESA, and the Hubble Heritage Team

A team led by astronomer Margot Brouwer (Leiden Observatory, The Netherlands) has tested the new theory of theoretical physicist Erik Verlinde (University of Amsterdam) for the first time through the lensing effect of gravity. Brouwer and her team measured the distribution of gravity around more than 33,000 galaxies to put Verlinde’s prediction to the test. She concludes that Verlinde’s theory agrees well with the measured gravity distribution. The results have been accepted for publication in the British journal Monthly Notices of the Royal Astronomical Society.

The gravity of galaxies bends space, such that the light traveling through this space is bent, as through a lens. Background galaxies that are situated far behind a foreground galaxy (the lens), thereby seem slightly distorted. This effect can be measured in order to determine the distribution of gravity around a foreground-galaxy. Astronomers have measured, however, that at distances up to a hundred times the radius of the galaxy, the force of gravity is much stronger than Einstein’s  of gravity predicts. The existing theory only works when invisible particles, the so-called dark matter, are added.

Verlinde now claims that he not only explains the mechanism behind gravity with his alternative to Einstein’s theory, but also the origin of the mysterious extra gravity, which astronomers currently attribute to dark matter. Verlinde’s new theory predicts how much gravity there must be, based only on the mass of the .

Brouwer calculated Verlinde’s prediction for the gravity of 33,613 galaxies, based only on their visible mass. She compared this prediction to the distribution of gravity measured by gravitational lensing, in order to test Verlinde’s theory. Her conclusion is that his prediction agrees well with the observed  distribution, but she emphasizes that dark matter could also explain the extra gravitational force. However, the mass of the dark matter is a free parameter, which must be adjusted to the observation. Verlinde’s theory provides a direct , without free parameters.

The new theory is currently only applicable to isolated, spherical and static systems, while the universe is dynamic and complex. Many observations cannot yet be explained by the new theory, so  is still in the race. Brouwer: “The question now is how the theory develops, and how it can be further tested. But the result of this first test definitely looks interesting.”